{"title":"Molecular Structure of Mesitylammonium Tetrafluoroborate","authors":"H. Reinke, I. Schicht, A. Schulz, A. Villinger","doi":"10.2116/ANALSCIX.24.X307","DOIUrl":null,"url":null,"abstract":"The title compound, MesNH3+BF4-·(CH3CN) (1) (Mes = 2,4,6-trimethylphenyl), crystallizes in the triclinic space group P1 with a = 8.5468(4), b = 12.9136(7), c = 13.2661(7)A, α = 64.303(3)°, β = 74.452(2)°, γ = 73.177(2)°, V = 1245.54(11)A3, Z = 2. The crystal packing is stabilized by strong interionic N-H…F and N-H…N hydrogen bonds between anions and cations, resulting in a three-dimensional network structure. One of the two tetrafluoroborate anions is disordered [site occupation factors 0.811(2) and 0.189(2)].","PeriodicalId":7796,"journal":{"name":"Analytical Sciences: X-ray Structure Analysis Online","volume":"18 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2008-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Analytical Sciences: X-ray Structure Analysis Online","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.2116/ANALSCIX.24.X307","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
The title compound, MesNH3+BF4-·(CH3CN) (1) (Mes = 2,4,6-trimethylphenyl), crystallizes in the triclinic space group P1 with a = 8.5468(4), b = 12.9136(7), c = 13.2661(7)A, α = 64.303(3)°, β = 74.452(2)°, γ = 73.177(2)°, V = 1245.54(11)A3, Z = 2. The crystal packing is stabilized by strong interionic N-H…F and N-H…N hydrogen bonds between anions and cations, resulting in a three-dimensional network structure. One of the two tetrafluoroborate anions is disordered [site occupation factors 0.811(2) and 0.189(2)].