Aquation reaction of iminodiacetate complex of oxidovanadium(IV) with 2,2’-bipyridine induced by Fe(III) ions: Kinetic studies

IF 2.1 4区 化学 Q3 CHEMISTRY, PHYSICAL
Joanna Drzeżdżon, Agnieszka Piotrowska-Kirschling, L. Chmurzyński, D. Jacewicz
{"title":"Aquation reaction of iminodiacetate complex of oxidovanadium(IV) with 2,2’-bipyridine induced by Fe(III) ions: Kinetic studies","authors":"Joanna Drzeżdżon, Agnieszka Piotrowska-Kirschling, L. Chmurzyński, D. Jacewicz","doi":"10.1177/1468678319850496","DOIUrl":null,"url":null,"abstract":"The kinetics of the aquation reaction of the [VO(ida)(bipy)]·2H2O (VO(ida)(bipy)) complex (where ida = iminodiacetate anion and bipy = 2,2’-bipyridine) promoted by [Fe(H2O)6]3+ ions were investigated in aqueous solutions. Spectrophotometric studies were carried out at different temperatures in the range of 293.15–313.15 K. The concentration of the [Fe(H2O)6]3+ (Fe3+) ions was kept within the range of 2 × 10–4 to 8 × 10–4 mol L–1, and the concentration of VO(ida)(bipy) was 1 × 10–3 mol L–1. The values of the observable reaction rate constants were calculated based on the Glint computer program. Furthermore, the mechanism for the aquation of VO(ida)(bipy), induced by Fe(III) ions, has been proposed.","PeriodicalId":20859,"journal":{"name":"Progress in Reaction Kinetics and Mechanism","volume":"65 1","pages":"300 - 306"},"PeriodicalIF":2.1000,"publicationDate":"2019-05-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Progress in Reaction Kinetics and Mechanism","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1177/1468678319850496","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0

Abstract

The kinetics of the aquation reaction of the [VO(ida)(bipy)]·2H2O (VO(ida)(bipy)) complex (where ida = iminodiacetate anion and bipy = 2,2’-bipyridine) promoted by [Fe(H2O)6]3+ ions were investigated in aqueous solutions. Spectrophotometric studies were carried out at different temperatures in the range of 293.15–313.15 K. The concentration of the [Fe(H2O)6]3+ (Fe3+) ions was kept within the range of 2 × 10–4 to 8 × 10–4 mol L–1, and the concentration of VO(ida)(bipy) was 1 × 10–3 mol L–1. The values of the observable reaction rate constants were calculated based on the Glint computer program. Furthermore, the mechanism for the aquation of VO(ida)(bipy), induced by Fe(III) ions, has been proposed.
铁离子诱导氧化钒(IV)与2,2′-联吡啶的亚氨基二乙酸配合物的水化反应动力学研究
研究了[Fe(H2O)6]3+离子在水溶液中促进[VO(ida)(bipy)]·2H2O (VO(ida)(bipy))配合物(ida =亚氨基二乙酸阴离子,bipy = 2,2′-联吡啶)的水化反应动力学。在293.15 ~ 313.15 K的不同温度下进行了分光光度研究。[Fe(H2O)6]3+ (Fe3+)离子浓度保持在2 × 10-4 ~ 8 × 10-4 mol L-1范围内,VO(ida)(bipy)浓度为1 × 10-3 mol L-1。利用Glint计算机程序计算了可观测到的反应速率常数。此外,还提出了由Fe(III)离子诱导VO(ida)(bipy)水化的机理。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 求助全文
来源期刊
CiteScore
2.10
自引率
0.00%
发文量
5
审稿时长
2.3 months
期刊介绍: The journal covers the fields of kinetics and mechanisms of chemical processes in the gas phase and solution of both simple and complex systems.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信