Thermocracking of a heavy fraction of the oil residue in a mixture with shale

Abstract

The process of tar thermal cracking in a mixture with crushed oil shale to obtain components of motor fuels and raw materials for the process of thermal cracking is investigated in this paper. The optimization results of technological parameters (shale concentration, temperature, and duration) are presented and the material balance (mass.%) of the process is made. It was found that during single-stage processing under relatively mild conditions (5 MPa, 425C, feed space velocity of 1.0 h-1), a deep destruction of tar is achieved (the yield of the gasoline fraction from boiling point to 200C is ~12 wt.%; medium distillates with boil. point 200370C-43-44 mass.%; raw materials for thermal cracking with boil. point above 370C ~15-16 wt.% on per the original tar). The generating coke-like products and the V and Ni contained in the raw materials are deposited on the mineral part of the shale and removed from the reaction zone with the liquid products of the process.