Study of molecular interactions between 2-methyl 1-propanol and m-substituted aniline at various temperatures (thermodynamic and acoustic properties)

Abstract

ABSTRACT Excess molar volumes (V E), excess acoustic impedance (Z E), excess isentropic compressibility (κ s E), deviation in viscosity (Δη), excess Gibbs energy of activation of viscous flow (G *E), excess free length (L f E), excess enthalpy (H E) and excess speed of sound (U E) for binary mixtures of 2-methyl-1-propanol with meta-substituted aniline (3-chloroaniline, 3-methoxyaniline and 3-methylaniline) at selected compositions were determined from the measured values of densities (ρ), viscosities (η) and speeds of sound (u) of pure components and their mixtures in range of 303.15–313.15 K. The results are analysed in terms of interactions arising due to the formation of complex hydrogen bond electron in the binary mixtures. Different theoretical models were applied to check the applicability to the present values of speed of sound and viscosity. Finally, the Prigogine–Flory–Patterson theory is applied to identify the most predominant molecular interaction.