{"title":"The effect of pH on the racemisation rate of 4,4′-biquinolyl","authors":"M. Crawford, R. Ingle","doi":"10.1039/J29710001907","DOIUrl":null,"url":null,"abstract":"The rate of racemisation of optically active 4,4′-biquinolyl varies only slightly from one solvent to another but drops about tenfold in strong acid. The effect is attributed mainly to alteration of the molecular dimensions on protonation.","PeriodicalId":17268,"journal":{"name":"Journal of The Chemical Society B: Physical Organic","volume":"72 1","pages":"1907-1912"},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society B: Physical Organic","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/J29710001907","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 1
Abstract
The rate of racemisation of optically active 4,4′-biquinolyl varies only slightly from one solvent to another but drops about tenfold in strong acid. The effect is attributed mainly to alteration of the molecular dimensions on protonation.
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