Creation of nanostructures via self-assembly at room temperature, cluster structures and dynamics, and bio-nano fusion technology

T. Maekawa
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Abstract

I show nanotechnology operated at room temperature focusing on the following three points; (a) Creation of nanostructures utilising near-critical fluids: The gas-liquid coexistence curves terminate at the critical point. As fluids approach their critical points, large molecular clusters are formed and as a result, the physical properties such as the specific heat and compressibility diverge. A variety of nanostructures are formed via self-assembly near the critical points. I show carbon onions, coils, fibres and other interesting structures created in near-critical carbon dioxide, ethane, xenon, benzene and their mixtures. (b) Structures and dynamics of clusters composed of magnetic particles: Various structures are formed by magnetic particles via anisotropic dipole-dipole interactions. The cluster structures and dynamics can be actively controlled by external magnetic fields such as dc, ac and rotational ones. I show self-organised structures and dynamics of clusters composed of ferromagnetic and superparamagnetic particles. (c) Application of cluster dynamics to the development of bio-medical devices: Biomolecules and cells can be labelled by magnetic particles and CNTs and therefore can be manipulated and sorted quite easily by applying external magnetic fields. Biomolecules and cells can also be manipulated utilising the magnetic hole effect, in which case labelling is not necessary. I explain a new nano/micro technology for a quick detection of diseases and allergies utilising the interactions between magnetic particles/CNTs and biomolecules/cells in external magnetic fields.
室温自组装纳米结构的创建,团簇结构和动力学,以及生物纳米融合技术
我展示了在室温下操作的纳米技术,重点是以下三点;(a)利用近临界流体制造纳米结构:气液共存曲线在临界点处终止。当流体接近临界点时,会形成大分子团簇,导致比热和可压缩性等物理性质发生偏离。在临界点附近通过自组装形成各种纳米结构。我展示了碳洋葱、线圈、纤维和其他有趣的结构,这些结构是在接近临界的二氧化碳、乙烷、氙、苯及其混合物中形成的。(b)由磁粒子组成的团簇的结构和动力学:磁粒子通过各向异性的偶极-偶极相互作用形成各种结构。在直流、交流、旋转等外部磁场的作用下,团簇结构和动力学可以得到主动控制。我展示了由铁磁和超顺磁粒子组成的团簇的自组织结构和动力学。(c)集群动力学在生物医疗装置开发中的应用:生物分子和细胞可以用磁性颗粒和碳纳米管进行标记,因此可以通过施加外部磁场很容易地进行操纵和分类。生物分子和细胞也可以利用磁孔效应进行操作,在这种情况下,不需要标记。我解释了一种新的纳米/微技术,用于利用磁性颗粒/碳纳米管与生物分子/细胞在外部磁场中的相互作用快速检测疾病和过敏。
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