A New Recycling Process of Waste Glass Wool Using Pyrolysis with Sodium Hydroxide

T. Wajima, S. Matsuka
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引用次数: 2

Abstract

Abstract—Glass wool insulation consists of glass fibers and phenolic resin as a binder to be a texture similar to wool, resulting in high thermal insulation properties. A large amount of them were used for energy conservation of buildings, and recently disposed at landfill sites to be pressured because of large volume to mass. In this study, we attempted to convert resin and glass fiber in the waste glass wool into gas and water glass using sodium hydroxide reaction, respectively. Waste glass wool was cut, sample peace (1 g) and sodium hydroxide (1 – 3 g) put into the reactor, and the reactor was heated with an electric furnace while flowing nitrogen (50 mL/min). After heating to setting temperature (400 550 oC) for 1 – 30 h, the reactor was naturally cooled to room temperature. The generated gas during the reaction was collected by gas pack. After cooling, the residue inside the reactor was washed with nitric acid, filtrates to obtain the residual substance, and silica concentration in the filtrate was measured to calculate the silica extracted content from waste glass wool. By using pyrolysis with sodium hydroxide, waste glass wool can be decomposed by converting the resin into the gases, such as hydrogen and methane, and glass fiber into soluble salt to be extracted into the solution. Waste glass wool can be decomposed by pyrolysis with 3 times weight of NaOH to the sample above 400 o C for 1 6 h.
氢氧化钠热解回收废玻璃棉新工艺
摘要:玻璃棉保温材料由玻璃纤维和酚醛树脂作为粘结剂组成,具有类似于羊毛的质地,因而具有较高的保温性能。其中大量用于建筑物的节能,最近由于体积比质量大而被处理在垃圾填埋场。在本研究中,我们尝试用氢氧化钠反应将废玻璃棉中的树脂和玻璃纤维分别转化为气玻璃和水玻璃。切割废玻璃棉,将样品和平(1 g)和氢氧化钠(1 ~ 3 g)放入反应器中,用电炉加热反应器,同时流氮(50 mL/min)。加热至设定温度(400 - 550℃)1 - 30小时后,反应器自然冷却至室温。反应过程中产生的气体由气包收集。冷却后,将反应器内的残渣用硝酸洗涤,滤液得到残渣,测定滤液中二氧化硅的浓度,计算废玻璃棉中二氧化硅的萃取量。利用氢氧化钠热解法,将树脂转化为氢气、甲烷等气体,将玻璃纤维转化为可溶盐提取到溶液中,对废玻璃棉进行分解。废玻璃棉在400℃以上用3倍质量的NaOH对样品热解16 h即可分解。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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