Management of Scale Control in Produced Water Reinjection - The Near Wellbore Scale Challenge Overcome

M. Jordan
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引用次数: 3

Abstract

Formation of sulphate and carbonate scale is well understood within the hydrocarbon extraction industry with injection of incompatible water such as seawater into reservoir with significant concentration of barium, strontium and calcium. To overcome this challenge chemical inhibition has been utilized for many decades and in the past 15 years elimination/reduction of the sulphate ion source from injection seawater using sulphate reduction membranes has been employed. This paper present laboratory work to qualify a scale inhibitor and field results of its application to prevent scale formation when an operator had to change from low sulphate seawater (LSSW) mixed with produced water (PW) for their water injection source to a blend of LSSW/PW and full sulphate seawater (SW). The increased level of sulphate presented a significant scale risk within the topside process on fluid mixing but more significantly increased the risk of scale formation within the near wellbore region of the injector wells which were under matrix injection rather than fracture flow regime. The qualification of a suitable inhibitor required assessment of the retention of a potentially suitable vinyl sulphonate co polymer scale inhibitors to ensure it had low adsorption and was able to propagate deep into the formation before being adsorbed from the supersaturated brine. Coreflood studies using reservoir core were carried out to assess the scale risk of the LSSW/PW/SW brine, propagation and release characteristic of the short-listed scale inhibitors. The recommendation that followed the laboratory studies was to apply a batch treatment of concentrated scale inhibitor to each injector well to provide a high concentration pad of scale inhibitor that would be transported into the reservoir when the scaling LSSW/PW/SW fluid was injected. Protection was provided by continuous application of the same chemical at minimum inhibitor concentration to prevent scale formation within the topside and the desorption of the batched inhibitor within the near wellbore would prevent scale formation within this critical region. Thirteen injection wells were treated with a pad of 10% vinyl sulphonate co polymer scale inhibitor to a radial distance of 3 ft. prior to the start of LSSW/PW/SW injection. Highly scaling brine has been injected now for 16 months into the thirteen wells at an average rate of 25,000 BWPD per well with no decline in injector performance observed. The lessons learned from this study are that changes in scaling potential within a PWRI system can be controlled by carrying out an assessment of location of scale formation and adoption of more typical production well scale squeezes treatment technology to protect the critical near wellbore region around PWRI injection wells.
采出水回注中结垢控制的管理——克服近井眼结垢难题
在油气开采行业中,通过向含有大量钡、锶和钙的储层注入海水等不相容水,可以形成硫酸盐和碳酸盐水垢。为了克服这一挑战,化学抑制已经使用了几十年,在过去的15年里,使用硫酸盐还原膜消除/减少了注入海水中的硫酸盐离子源。本文介绍了一种阻垢剂的实验室工作,以及当作业者不得不将低硫酸盐海水(LSSW)与采出水(PW)的混合注入水源改为LSSW/PW与全硫酸盐海水(SW)的混合注入水源时,该阻垢剂用于防止结垢的现场应用结果。硫酸盐含量的增加在上部过程中对流体混合产生了显著的结垢风险,但在基质注入而非压裂流动状态下,更显著地增加了注入井近井眼区域结垢的风险。确定合适的阻垢剂需要评估潜在合适的乙烯磺酸共聚物阻垢剂的保留率,以确保其具有低吸附性,并且能够在从过饱和盐水中吸附之前深入地层。利用储层岩心进行了岩心驱替研究,以评估LSSW/PW/SW卤水的结垢风险,以及入围阻垢剂的扩散和释放特性。实验室研究之后的建议是,对每口注入井进行一次浓缩阻垢剂的批量处理,以提供高浓度的阻垢剂垫块,当注入LSSW/PW/SW结垢液时,这些阻垢剂将被输送到储层中。在最小的抑制剂浓度下,连续使用相同的化学物质,以防止上层结垢,在近井内的批处理抑制剂的解吸可以防止这一关键区域的结垢。在开始注入LSSW/PW/SW之前,对13口注入井进行了10%乙烯磺酸共聚物阻垢剂的处理,井眼径向距离为3英尺。目前,高结垢盐水已在13口井中注入了16个月,平均每口井的速度为25000 BWPD,未观察到注入器性能下降。从这项研究中得到的经验教训是,PWRI系统中结垢潜力的变化可以通过对结垢地层的位置进行评估和采用更典型的生产井结垢挤压处理技术来控制,以保护PWRI注水井周围的关键近井区域。
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