Wafer size MOS2 with few monolayer synthesized by H2S sulfurization

Yen-Teng Ho, Y. Chu, Lin‐Lung Wei, T. Luong, Chih-Chien Lin, Chun-Hung Cheng, Hung-Ru Hsu, Y. Tu, E. Chang
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Abstract

Wafer sized, high quality continuous films would be a key demand for MoS2 implemented in circuit application. In this study, the growth of few monolayer MoS2 on 4 inches SiO2/Si substrate were demonstrated. The MoS2 thin films were synthesized by sulfurized in a furnace from the ultra-thin MoO3 starting materials by using H2S. The obtained MoS2 thin film examined by Raman analysis and Photoluminescence (PL), shows the semiconductor nature with direct transition peaks of 1.86 eV and 1.99 eV. The 4∼5 monolayer of MoS2 with thickness around 2.6 nm is confirmed by cross-sectional view of transmission electron microscopy (TEM). Additionally, the DC characteristics of MoS2 MOSFETs exhibit at least 2 order in on/off current ratio, demonstrating the feasibility for circuit application.
用硫化氢硫化法制备了硅片尺寸的单元化二硫化钼
晶圆尺寸的高质量连续薄膜将是MoS2在电路应用中实现的关键需求。在本研究中,研究了在4英寸SiO2/Si衬底上生长少量单层MoS2。以超薄MoO3为原料,采用硫化氢在炉内硫化法制备了MoS2薄膜。通过拉曼光谱和光致发光(PL)检测得到的MoS2薄膜具有半导体性质,其直接跃迁峰为1.86 eV和1.99 eV。透射电子显微镜(TEM)的横截面图证实了厚度约为2.6 nm的4 ~ 5 MoS2单层。此外,MoS2 mosfet的直流特性表现出至少2阶的开/关电流比,证明了电路应用的可行性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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