Analysis of the impact of man-made harmful waste on the soil by X-ray fluorescence method

A. B. Myrzabaev, D. Golovanov, Jacek Urbanіak, Sultan Asanbaevich Kusherbayev, M. Bodeyev
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Abstract

As the technogenic load increases from year to year, the soil loses its ability to provide plants with various nutrients, air, water, heat, biological and physico-chemical environment. The reason is an increase in heavy metal compounds in the soil, which leads to its degradation. The presence of heavy metals in the ecosystem, such as Pb, Cr, As, is toxic to humans and biosystems even at low concentrations. Anthropogenic pollution of the environment by heavy metals (industry, mining and smelting of ores, transport, agriculture) increases over time. Currently, soil contamination with heavy metals and its impact on the biosphere are increasingly being studied. This is especially observed in large industrially urbanized regions, where there is a large accumulation of hazardous waste that does not decompose in nature and is stored for a long time. To identify anthropogenic pollution of the environment with heavy metals, samples were taken from various soil horizons of the city of Zhezkazgan and adjacent regions. The chemical compositions of the taken samples were determined by X-ray fluorescence. Analytical work was carried out in the laboratory of the Department of Landscape Geochemistry and Soil Geography of Lomonosov Moscow State University. We analyzed the quantitative content of chemical elements in the soils of Zhezkazgan and adjacent zones I (As, Zn, Cd, Pb, Hg, Se), II (Co, Ni, Mo, Cu, Cr), III (Ba, V, W, Mn, Sr) hazard levels.
x射线荧光法分析人为有害废弃物对土壤的影响
随着技术负荷的逐年增加,土壤失去了向植物提供各种养分、空气、水、热、生物和物理化学环境的能力。原因是土壤中重金属化合物增加,导致土壤退化。生态系统中存在的重金属,如铅、铬、砷,即使浓度很低,也会对人类和生物系统产生毒性。重金属对环境的人为污染(工业、采矿和冶炼矿石、运输、农业)随着时间的推移而增加。目前,土壤重金属污染及其对生物圈影响的研究日益深入。这一点在大型工业城市化地区尤其明显,那里有大量的危险废物积聚,这些废物在自然界中不分解,而且储存时间很长。为查明环境中重金属的人为污染,对浙卡兹干市及邻近地区的不同土壤层位进行了采样。采用x射线荧光法测定了样品的化学成分。分析工作是在罗蒙诺索夫莫斯科国立大学景观地球化学和土壤地理学系的实验室进行的。分析了浙扎卡兹干及其邻区土壤中I (As、Zn、Cd、Pb、Hg、Se)、II (Co、Ni、Mo、Cu、Cr)、III (Ba、V、W、Mn、Sr)化学元素含量的危害程度。
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