One-pot Chemical Synthesis and Characterization of Fluorescent Cd/Znse Quantum Dots Using L-Cysteine as Stabilizing Agent

Joy Sebastian Prakash Joseph Irudayaraj, Prakash Thanigainathan, M. Ramach, Karunanithi Rajamanickam
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Abstract

Cd/ZnSe quantum dots (QDs) were synthesized in a wet chemical method by using a stabilizing agent L-cysteine. This facile synthesis does not require any high temperature or inert gas atmosphere. The synthesized QDs were characterized by using UV-Vis spectrophotometer, spetrofluorometer, fourier transform infrared (FT-IR) spectrometer, Fluorescence lifetime spectrometer, thermogravimetric analysis (TGA), powder x-ray diffraction, transmission electron microscopy and scanning electron microscopy. The synthesized QDs are spherical in shape with an average diameter of 4.78 nm and are readily soluble in water, making them biologically compatible. Further, the carboxyl and amine functional groups are accessible on the QDs’ surface. Thus, these QDs can be used as molecular imaging probes by anchoring targeting molecules by using the functional groups available on the surface of the QDs.
以l -半胱氨酸为稳定剂的荧光Cd/Znse量子点的一锅化学合成及表征
以l -半胱氨酸为稳定剂,采用湿化学方法合成了Cd/ZnSe量子点。这种简单的合成不需要任何高温或惰性气体气氛。利用紫外-可见分光光度计、荧光光谱仪、傅里叶变换红外光谱仪、荧光寿命光谱仪、热重分析(TGA)、粉末x射线衍射、透射电镜和扫描电镜对合成的量子点进行了表征。合成的量子点呈球形,平均直径为4.78 nm,易溶于水,具有生物相容性。此外,羧基和胺官能团在量子点表面是可接近的。因此,这些量子点可以作为分子成像探针,利用量子点表面可用的官能团锚定目标分子。
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