Urey-Bradley-Kraftkonstanten und andere Schwingungseigenschaften des Trithiocarbonat-Ions

Abstract

Urey-Bradley force constants, Coriolis coupling coefficients, and mean amplitudes of vibration were calculated for the CS₃²⁻ ion from infra-red and Raman spectroscopic data. The force constants are in accordance with orbital valence force field values. The calculated values for the coupling coefficients and the vibration amplitudes were found to be very similar to the corresponding values for BCl₃.