Characteristics of Trace Elements in Molybdenite and Its Application in Mineral Deposits

Sun Pengcheng, Li Chao, Zhou Li-min, Q. Wenjun, Liao Xinwei, Zhao Hong, Du Andao
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Abstract

Previous studies on molybdenite are mainly focused on Re-Os dating for a deposit, by contrast there have relatively little on trace elements in molybdenite. On the basis of statistical summarizing the previous research results, this paper discusses the variation of trace elements of molybdenite in various deposits and the combination of the different trace elements in molybdenite of different deposits, which is expected to expand its application in mineral deposit science. The results show that Re and W contents in molybdenite have the potential to be used as tracer to trace its sources. Molybdenite in different types of deposits has different trace elements composition and content, which mainly depends on the ore-forming fluids. Trace elements exist in various states in molybdenite, including isomorphic substitution, inclusion, adsorption and so on. Elements such as Re, W, Se, Te and Nb can enter the molybdenite lattice by replacing Mo or S, while Pb, Zr, Fe and REE those elements mainly appear as mineral inclusions. Most trace elements (for Fe, Cu, Te, etc.) are positively correlated, which may indicate that their sources are in similiar among each other. A few trace elements were negatively correlated with each other, which may reflect the different in their sources.
辉钼矿中微量元素特征及其在矿床中的应用
以往对辉钼矿的研究主要集中在矿床的Re-Os定年,而对辉钼矿中微量元素的研究相对较少。本文在统计总结前人研究成果的基础上,探讨了不同矿床辉钼矿中微量元素的变化规律以及不同矿床辉钼矿中不同微量元素的组合规律,以期扩大其在矿床科学中的应用。结果表明,辉钼矿中稀土和钨的含量有可能作为辉钼矿来源的示踪剂。不同类型矿床中的辉钼矿具有不同的微量元素组成和含量,这主要取决于成矿流体。微量元素在辉钼矿中以多种形态存在,包括同构取代、包合、吸附等。Re、W、Se、Te、Nb等元素可以取代Mo或S进入辉钼矿晶格,Pb、Zr、Fe、REE等元素主要以矿物包裹体的形式出现。大多数微量元素(如Fe、Cu、Te等)呈正相关,这可能表明它们的来源相似。少数微量元素呈负相关,可能反映了其来源的不同。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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