Phenylvinylidene RePt Complexes Containing Diphenylphosphine Ligands at the Platinum Atom: Synthesis, IR, NMR Spectroscopic and Electrochemical Properties
O. S. Chudin, V. V. Verpekin, G. V. Burmakina, Dmitry V. Zimonin, A. Kondrasenko, A. I. Rubaylo
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引用次数: 0
Abstract
The μ-phenylvinylidene complexes Cp(CO)2RePt(μ-C=CHPh)(PPh2H)(L) [L = PPh3 (1), P(OPri)3 (2)] were synthesized for the first time. Their IR, NMR spectroscopic and redox properties were studied. Based on IR, NMR spectroscopic data their molecular structures were proposed. The pathways of redox-reactions of the complexes were determined