Modelling Moisture Sorption Isotherms of Superabsorbent Polymer Fabric for Desiccant Drying of Crops

P. Kimani, A. Gitau, D. Mbuge, J. O. Agullo
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Abstract

Desiccants are important in the drying of temperature-sensitive grains such as seeds for planting. Superabsorbent polymers (SAPs) have previously been identified for possible application in the drying of crops. Applying the gravimetric technique to measure the sorption isotherms and the effectiveness of the desiccant in crop drying was determined at temperatures 20, 25, 30, 35, 40, 45, 50, and 55°C. Using R statistical software, eleven sorption isotherm models were fitted to the experimental data using the nonlinear regression functions. The coefficients of each model were obtained. The modified Freundlich, modified Henderson, and modified Oswin models best predicted the experimental data for the study temperature range. Using symbolic regression and nonlinear regression in R software, four mathematical models were obtained. R software codes were assembled for the analysis of sorption isotherm models. Compared to the existing models, the developed models were found to give a more statistically accurate association between the temperature, moisture content of SAP fabric, and relative humidity.
用于农作物干燥剂干燥的高吸水性聚合物织物吸湿等温线建模
干燥剂在干燥对温度敏感的谷物(如播种种子)时很重要。高吸水性聚合物(sap)先前已被确定为可能应用于作物干燥。在20、25、30、35、40、45、50和55°C的温度下,应用重量法测量了干燥剂在作物干燥中的吸附等温线和有效性。利用R统计软件,利用非线性回归函数对实验数据拟合了11个吸附等温线模型。得到了各模型的系数。修正的Freundlich、修正的Henderson和修正的Oswin模型最能预测研究温度范围的实验数据。利用R软件中的符号回归和非线性回归,得到了四种数学模型。编写了用于吸附等温线模型分析的R软件代码。与现有模型相比,所开发的模型在统计上更准确地描述了SAP织物的温度、含水率和相对湿度之间的关联。
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