Calcination and Pelletizing of Siderite Ore

Mehmet Çelikdemir, M. Sarıkaya, T. Depci, RamazanAydogmus, A. Yucel
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Abstract

In the present study, calcination properties of Hekimhan-Deveci siderite (FeCO 3 ) ore and the effect of calcination process before the pelletization on strength of pellet were inves tigated and evaluated. Two different calcination processes were followed. One of them is the traditional calcination process and the other one is microwave assisted calcination process which is a new process for siderite ore. The characterization of the calcined and uncalcined siderite ore was done using X-ray diffraction, X-ray fluorescence spectrom etry and thermogravimetric analysis. The physical and mechanical properties of pellets which were obtained using the raw siderite and the calcined siderite were compared with each other. As a result of experimental studies, it was found that the calcination process decreased the milling time, causing the significant energy saving and the most suitable calcination process for siderite ore was found as 15 min at 700°C temperature. It was the first time that the calcination process of the siderite ore was achieved by microwave by adding 30 wt% sucrose as a thermal auxiliary. The microwave conditions were deter - mined as 900 W at 3 min. In 3 min, the temperature of the siderite ore increased up to 1100°C and 32.14% weight loss for the sample was achieved. different bentonite ratios (8, 9, 10, 11, 12%) to the raw siderite and the calcined siderite which were milled for 90 and 60 min, respectively. The raw pellets were heated at a temperature of 1300°C which is the recrystallization temperature of hematite. Recrystallization was confirmed by SEM images and the process was confirmed to be successful. The product pellets were tested for compressive strength. The highest level of pellet strength was determined from the material obtained by grinding calcined siderite for 90 min. This pellet, which has a maximum strength value of 268 kgf, has an average durability of 28% higher than the pellet of the raw siderite.
菱铁矿的煅烧和造球
研究并评价了Hekimhan-Deveci菱铁矿(feco3)矿的煅烧性能以及球团前煅烧工艺对球团强度的影响。采用了两种不同的煅烧工艺。一种是传统的煅烧工艺,另一种是菱铁矿的新工艺——微波辅助煅烧工艺。利用x射线衍射、x射线荧光光谱和热重分析对煅烧和未煅烧的菱铁矿进行了表征。对用原菱铁矿和煅烧菱铁矿制备的球团的物理力学性能进行了比较。通过实验研究发现,该焙烧工艺缩短了磨矿时间,节能效果显著,在700℃温度下焙烧15 min为菱铁矿的最佳工艺。首次在微波条件下,通过添加30% wt%的蔗糖作为热助剂,实现了菱铁矿的煅烧过程。微波条件为900 W,加热3 min。在3 min内,菱铁矿的温度升高到1100℃,样品失重32.14%。膨润土与原菱铁矿和焙烧菱铁矿的比例分别为8、9、10、11、12%,磨矿时间分别为90min和60min。原料球团在1300℃的温度下加热,这是赤铁矿的再结晶温度。通过扫描电镜图像证实了再结晶,并证实了该工艺是成功的。对产品球团进行了抗压强度测试。最高强度的球团是由煅烧菱铁矿研磨90分钟得到的材料确定的。该球团的最大强度值为268 kgf,平均耐久性比原菱铁矿球团高28%。
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