Physicochemical Properties of Diacetylenic Light Fuel Oil from Congolese Oleaginous Plant Ongokea gore (Hua) Pierre

J. Ntumba, A. Mulula, K. T. Kashishi, M. N. Mifundu, R. Robiette, K. Taba
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引用次数: 4

Abstract

Vegetable oil-based fuels are promising alternative fuels for diesel and light fuel engines because of their environmental and economic strategic advantages. In this study, Ongokea gore oil (OGO) and its fully hydrogenated oil were transesterified by means of ethanol in the presence of sodium ethoxide. Fatty acid ethyl esters (FAEE) products were confirmed by 1H NMR and characterized by physical-chemical methods in accordance with the ASTM D 6751 and AFNOR M 15-009 specifications for biodiesels and light biofuels. These methods concern determination of color, density, viscosity, flash and pour points, ash, water and sulfur contents, and corrosion on copper. It was found that pure fatty acid ethyl esters of Ongokea gore oil (B100) and its hydrogenated oil (B100-H) meet standard requirements for most of the biodiesel characteristics studied. Only the kinematic viscosity and density values were outside recommended biodiesel standard limits which makes them unsuitable for use in diesel engines. In accordance with the AFNOR M 15-009 specifications of light fuels, they can be used in light fuel engines. Physical-chemical properties of B20, a FAEE blend in petrodiesel, are within the limits prescribed for petrodiesel standards. In brief, Ongokea gore seeds, a nonedible and high-oil-producing feedstock, are suitable starting material for production of light biofuel. The latter blends in petrodiesel can be used as fuel in diesel engines.
刚果产油植物Ongokea gore (Hua) Pierre产二乙基轻燃料油的理化性质
植物油基燃料由于其环境和经济战略优势,是柴油和轻型燃料发动机的有前途的替代燃料。本研究以乙醇为原料,在乙氧化钠的存在下,对乌龙果油及其完全氢化油进行酯交换反应。脂肪酸乙酯(FAEE)产品经1H NMR确认,并根据生物柴油和轻型生物燃料的ASTM D 6751和AFNOR M 15-009规范采用物理化学方法进行表征。这些方法涉及铜的颜色、密度、粘度、闪点和倾点、灰分、水和硫含量以及腐蚀的测定。研究发现,龙骨油(B100)及其氢化油(B100- h)的纯脂肪酸乙酯满足大多数生物柴油特性的标准要求。只有运动粘度和密度值超出了推荐的生物柴油标准限制,这使得它们不适合用于柴油发动机。根据AFNOR M 15-009轻燃料规范,它们可用于轻燃料发动机。B20是一种FAEE混合汽油柴油,其理化性能在汽油柴油标准规定的范围内。总之,龙葵种子是一种不可食用的高产油原料,是生产轻型生物燃料的合适原料。后者与石油柴油混合后可用作柴油发动机的燃料。
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