Electrochemical synthesis of Tb3+ waterless luminescent complex compounds with some fluorine-containing aromatic carboxylic acids

A. Oflidi
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Abstract

Electrochemical synthesis of terbium (III) waterless complex compounds with fluorine-containing aromatic carboxylic acids of TbL3 content was performed. The structure of obtained complex compounds coordination site was studied using the IR-spectroscopy method, and it was found out, that the coordination between used ligands and Tb3+ ions is bidentate. We also studied luminescent properties of the obtained compounds and showed that the terbium (III) with pentafluorobenzoic acid complex compound has the highest luminescent efficiency.
含氟芳香羧酸的Tb3+无水发光配合物的电化学合成
采用电化学方法合成了含TbL3的含氟芳香羧酸型铽(III)无水配合物。用红外光谱法研究了得到的配合物配位位点的结构,发现所使用的配体与Tb3+离子之间的配位是双齿的。我们还研究了所得到的化合物的发光性能,结果表明,铽(III)与五氟苯甲酸配合物的发光效率最高。
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