Study on Corrosion Failure Characteristics of Silicone Rubber in Acidic Environment

Xiaodan Ma, Zhijin Zhang, Xiaohong Ma, Huan Huang, Xingliang Jiang
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Abstract

In order to grasp the corrosion failure characteristics of silicone rubber in an acidic environment, an artificial mist box was used to artificially simulate the corrosion conditions acting on the silicone rubber, and the changes in its surface characteristics were analyzed. The research results show that under the combined action of acid mist and electric field, the physical and chemical properties of composite insulators have declined. There are holes and cracks on the surface, and the hardness increases with the corrosion time. Before flashover, if there is no obvious discharge in the withstand voltage process, the contact angle, relative dielectric constant and absorption peak area change little with the increase of corrosion time. The analysis shows that the damage rate of large-area corrosion of silicone rubber is very slow. Acidic substances will cause the main chain and side chains of the silicone rubber to break, and the aluminum hydroxide in the silicone rubber also reacts with strong acids, resulting in the destruction of the structure of the silicone rubber. The physical and chemical properties are reduced.
硅橡胶在酸性环境中的腐蚀失效特性研究
为了掌握硅橡胶在酸性环境中的腐蚀失效特征,采用人工雾箱对作用于硅橡胶的腐蚀条件进行人工模拟,分析其表面特性的变化。研究结果表明,在酸雾和电场的共同作用下,复合绝缘子的理化性能有所下降。表面有孔洞和裂纹,硬度随腐蚀时间的延长而增大。闪络前,若耐压过程中无明显放电,接触角、相对介电常数和吸收峰面积随腐蚀时间的增加变化不大。分析表明,硅橡胶大面积腐蚀的损伤速率非常缓慢。酸性物质会使硅橡胶的主链和侧链断裂,硅橡胶中的氢氧化铝也会与强酸发生反应,造成硅橡胶结构的破坏。物理和化学性质降低。
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