Transition metal ions in zeolites: siting and energetics of Cu2+

IF 9.3 2区化学 Q1 CHEMISTRY, PHYSICAL

Catalysis Reviews-Science and Engineering Pub Date : 1993-01-01 DOI:10.1080/01614949308013908

R. Schoonheydt

引用次数: 152

Abstract

Abstract In this review only exchangeable cations on extralattice positions in zeolites are considered. Cu2+ is used as a probe for the siting, the nature, and the energy of the bonding to the lattice. The term zeolite encompasses the crystalline aluminosilicates and the crystalline aluminum phosphates (ALPO) with ion exchange and molecular sieving properties. However, exchangeable cations in isomorphously substituted ALPOs have not been studied systematically and are not treated here.

查看原文本刊更多论文

沸石中的过渡金属离子:Cu2+的定位和能量学

摘要本文只讨论沸石中晶格外位置的交换阳离子。Cu2+被用作定位、性质和与晶格键合能量的探针。沸石一词包括具有离子交换和分子筛分特性的结晶硅酸铝和结晶磷酸铝(ALPO)。然而，在同构取代的ALPOs中，交换阳离子尚未被系统地研究过，本文也不作讨论。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文求助全文

来源期刊

Catalysis Reviews-Science and Engineering 化学-物理化学

CiteScore

22.30

自引率

2.80%

发文量

期刊介绍： Catalysis Reviews is dedicated to fostering interdisciplinary perspectives in catalytic science and engineering, catering to a global audience of industrial and academic researchers. This journal serves as a bridge between the realms of heterogeneous, homogeneous, and bio-catalysis, providing a crucial and critical evaluation of the current state of catalytic science and engineering. Published topics encompass advances in technology and theory, engineering and chemical aspects of catalytic reactions, reactor design, computer models, analytical tools, and statistical evaluations.