Synthesis and characterization of a highly cross linked PEGME and PEG for solid electrolyte and its application in dye-sensitized solar cells

M. S. Akhtar, Ji-min Chun, Hyun-Chul Lee, Ki-Ju Kim, O. Yang
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Abstract

PEG for solid electrolyte and its application in dye-sensitized solar cells M. Shaheer Akhtar, Ji-min Chun, Hyun-Chul Lee, Ki-Ju Kim and O-Bong Yang School of the Environmental and Chemical Engineering, Chonbuk National University, Jeon-Ju Abstract In this paper, we were prepared a highly cross linked polymer with poly (ethylene glycol) methyl ether (PEGME) and poly ethylene glycol (PEG) in presence of inorganic salts by chemical method and used as polymer electrolyte with the addition of iodide couple. This electrolyte is showing ambient ionic conductivity of 2.35 mS/cm, it is comparably well high to reported electrolyte. Solid state dye sensitized solar were fabricated with this polymer electrolyte and achieved an open circuit voltage of 0.616 volt, short circuit current of 8.96 mA/cm and over all conversion efficiency of about 3% under light intensity of 100mW/cm.
高交联聚乙二醇和固体电解质聚乙二醇的合成、表征及其在染料敏化太阳能电池中的应用
固体电解质PEG及其在染料敏化太阳能电池中的应用M. Shaheer Akhtar, Ji-min Chun, Hyun-Chul Lee, Ki-Ju Kim, O-Bong Yang以聚乙二醇甲基醚(PEGME)和聚乙二醇(PEG)为原料,在无机盐存在下,通过化学方法制备了高交联聚合物,并添加碘离子偶联作为聚合物电解质。该电解质显示出2.35 mS/cm的环境离子电导率,与报道的电解质相比相当高。用该聚合物电解质制备了固态染料敏化太阳能,在100mW/cm光强下,开路电压为0.616伏,短路电流为8.96 mA/cm,总体转换效率约为3%。
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