Intramolecular Cyclopropanation of Unsaturated Terminal Epoxides

IF 14.4 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Journal of the American Chemical Society Pub Date : 2004-06-24 DOI:10.1021/ja047346k

David M. Hodgson, Ying Kit Chung, Jean-Marc Paris

引用次数: 52

Abstract

Efficient lithium amide-induced intramolecular cyclopropanation of bishomoallylic and trishomoallylic epoxides is described. The methodology is used in an asymmetric synthesis of sabina ketone.

Abstract Image

查看原文本刊更多论文

不饱和末端环氧化物的分子内环丙烷化反应

描述了锂酰胺诱导的双聚和三聚环氧化合物的分子内环丙烷化反应。该方法用于不对称合成萨比娜酮。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文求助全文

来源期刊

Journal of the American Chemical Society 化学-化学综合

CiteScore

24.40

自引率

6.00%

发文量

2398

审稿时长

1.6 months

期刊介绍： The flagship journal of the American Chemical Society, known as the Journal of the American Chemical Society (JACS), has been a prestigious publication since its establishment in 1879. It holds a preeminent position in the field of chemistry and related interdisciplinary sciences. JACS is committed to disseminating cutting-edge research papers, covering a wide range of topics, and encompasses approximately 19,000 pages of Articles, Communications, and Perspectives annually. With a weekly publication frequency, JACS plays a vital role in advancing the field of chemistry by providing essential research.