Removing of carmoisine dye pollutant from contaminated waters by photocatalytic method using a thin film fixed bed reactor

Dariush Elami, K. Seyyedi
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引用次数: 10

Abstract

Abstract Recently, the advanced oxidation processes have been used to treat wastewater containing various dye pollutants via various methods of purification. In this work, the removal of the Carmoisine dye from contaminated waters by a photocatalytic method in a recirculating thin-film fixed bed reactor (TFFBR) was investigated and was compared with photolysis. By the surface response method via Minitab software, the experiments were designed in such a way that the effects of different parameters on the process were studied. The effect of various parameters, for instance, pH of solution, reaction time, initial dye concentration, flow rate, hydrogen peroxide concentration on the dye removal efficiency has been investigated. By the screening and optimization stages in the response surface method, the optimal conditions for performing the process were as follows: 45 min of time, pH 2, 13.33 mM of H2O2 concentration, the flow rate of 0.25 Lmin−1, and 10 mg/L of dye concentration. The proficiency of removing color by advanced oxidation is more than 97% under optimum conditions. Graphical Abstract
薄膜固定床反应器光催化法去除污染水体中的卡莫辛染料污染物
摘要近年来,高级氧化工艺已被用于处理含有各种染料污染物的废水,并通过各种净化方法进行处理。在循环式薄膜固定床反应器(TFFBR)中研究了光催化法去除污染水体中的卡莫辛染料,并与光解法进行了比较。通过Minitab软件,采用表面响应法设计实验,研究了不同参数对工艺的影响。考察了溶液pH、反应时间、染料初始浓度、流速、双氧水浓度等参数对染料去除率的影响。通过响应面法的筛选和优化阶段,最佳工艺条件为:时间45 min, pH 2, H2O2浓度13.33 mM,流速0.25 Lmin−1,染料浓度10 mg/L。在最佳条件下,深度氧化法脱色率可达97%以上。图形抽象
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