Sorption of Ni(II) and Cr(III) ions by the Chironomus yoshimatsui larvae from wastewater

K. Ryoo
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Abstract

In this study, Chironomus yoshimatsui larvae were applied to remove Ni(II) and Cr(III) ions from wastewater. The sorption studies were carried out using laboratory-reared C. y. larvae. It was found that C. y. larvae are very susceptible to Cr(III) as compared to Ni(II). The survival capacity of C. y. larvae was sharply reduced when exposed to even low Cr(III) concentration. Sorption isotherm and kinetics of C. y. larvae for Ni(II) were determined by means of controlled experiments in a batch system. It was observed that sorpyion efficiency of Ni(II) was largely concentration dependent and more effective at lower concentration. At each equilibrium, Ni(II) was removed up to roughly 44∼80 %. Sorption data were better fitted to the Langmuir isotherm model because of its correlation coefficient R2 value greater than that of the Freundlich isotherm model. The sorption kinetics by C. y. larvae for Ni(II) was well described a pseudo-first-order rate expression. C. y. larvae have enormous potential for application in wastewater treatment technologies because they are widespread and abundant all around the world and can be easily kept in culture.
吉松Chironomus yoshimatsui幼虫对废水中Ni(II)和Cr(III)离子的吸附
本研究采用吉松Chironomus yoshimatsui幼虫去除废水中的Ni(II)和Cr(III)离子。吸附研究采用实验室饲养的c.y.幼虫进行。结果表明,与Ni(II)相比,cyly幼虫对Cr(III)非常敏感。即使暴露于低浓度的Cr(III)环境中,幼虫的存活能力也急剧下降。采用间歇式对照实验法测定了幼蚊对Ni(II)的吸附等温线和吸附动力学。结果表明,Ni(II)的吸附效率与浓度密切相关,在较低浓度下吸附效果更好。在每个平衡状态下,Ni(II)被去除约44¼80%。Langmuir等温线模型的相关系数R2值大于Freundlich等温线模型,因此吸附数据更适合于Langmuir等温线模型。幼虫对Ni(II)的吸附动力学被很好地描述为伪一级速率表达式。幼虫在世界范围内分布广泛,数量丰富,且易于培养,在污水处理技术中具有巨大的应用潜力。
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