Suggestion for search of cyclopropenone (c-C3H2O) in a cosmic object

Q2 Physics and Astronomy
M.K. Sharma , M. Sharma , S. Chandra
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引用次数: 7

Abstract

Following Minimum Energy Principle, out of the three isomers of chemical formula C3H2O, the cyclopropenone (c-C3H2O) is the most stable and therefore may be the most abundant and easily detectable in a cosmic object. The cyclopropenone is detected in Sgr B2(N). Owing to half-spin of each of two hydrogen atoms, the c-C3H2O has two distinct ortho and para species. Using the rotational and centrifugal distortion constants along with the electric dipole moment, we have calculated energies of 100 rotational levels of each of the ortho and para species of c-C3H2O and the Einstein A-coefficients for radiative transitions between the levels. The values of Einstein A-coefficients along with the scaled values for collisional rate coefficients are used for solving a set of statistical equilibrium equations coupled with the equations of radiative transfer.

Brightness temperatures of seven rotational transitions of each of the ortho and para species of c-C3H2O are investigated. Out of fourteen transitions, seven are found to show anomalous absorption and rest seven are found to show emission feature. We find that the transitions 110111 (1.544  GHz) may play important role in identification of cyclopropenone in a cosmic object.

在宇宙物体中寻找环丙烯(c-C3H2O)的建议
根据最小能量原理,在化学式C3H2O的三个同分异构体中,环丙烯(c-C3H2O)是最稳定的,因此在宇宙物体中可能是最丰富和最容易检测到的。在Sgr B2(N)中检测到环丙烯。由于两个氢原子各有半自旋,c-C3H2O具有两个不同的邻位和对位基团。利用旋转和离心畸变常数以及电偶极矩,我们计算了c-C3H2O的每个正对偶种的100个旋转能级的能量,以及能级之间辐射跃迁的爱因斯坦a系数。利用爱因斯坦a系数的值和碰撞速率系数的标度值,求解了一组与辐射传递方程耦合的统计平衡方程。研究了c-C3H2O各邻位和对位的7个旋转跃迁的亮度温度。在14个跃迁中,有7个表现出异常吸收,其余7个表现出发射特征。我们发现110 ~ 111 (1.544 GHz)的跃迁可能对宇宙物体中环丙烯的识别起重要作用。
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来源期刊
Molecular Astrophysics
Molecular Astrophysics ASTRONOMY & ASTROPHYSICS-
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期刊介绍: Molecular Astrophysics is a peer-reviewed journal containing full research articles, selected review articles, and thematic issues. Molecular Astrophysics is a new journal where researchers working in planetary and exoplanetary science, astrochemistry, astrobiology, spectroscopy, physical chemistry and chemical physics can meet and exchange their ideas. Understanding the origin and evolution of interstellar and circumstellar molecules is key to understanding the Universe around us and our place in it and has become a fundamental goal of modern astrophysics. Molecular Astrophysics aims to provide a platform for scientists studying the chemical processes that form and dissociate molecules, and control chemical abundances in the universe, particularly in Solar System objects including planets, moons, and comets, in the atmospheres of exoplanets, as well as in regions of star and planet formation in the interstellar medium of galaxies. Observational studies of the molecular universe are driven by a range of new space missions and large-scale scale observatories opening up. With the Spitzer Space Telescope, the Herschel Space Observatory, the Atacama Large Millimeter/submillimeter Array (ALMA), NASA''s Kepler mission, the Rosetta mission, and more major future facilities such as NASA''s James Webb Space Telescope and various missions to Mars, the journal taps into the expected new insights and the need to bring the various communities together on one platform. The journal aims to cover observational, laboratory as well as computational results in the galactic, extragalactic and intergalactic areas of our universe.
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