Different Preparation Methods of Ni-FAU(Y) Zeolite for Nitric Oxide Reduction

P. Worathanakul, N. Rakpasert
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引用次数: 2

Abstract

The effect of Ni cation supported on FAU(Y) zeolite was prepared by aqueous solution ion exchange and incipient wetness impregnation methods in the selective catalytic reduction of nitric oxide using hydrogen as the reactant in packed bed reactor. 0.5 and 3.5 wt% of Ni (II) metals were loaded in the FAU(Y) zeolite. The samples were characterized by X-ray diffraction, X-ray fluorescence and scanning electron microscope. The obtained Ni/FAU has enlarged pore size of octahedral shaped crystals with approximately 0.22 ± 0.085 μm diameter. Ni loading did not change the structure of FAU(Y) zeolite. Ni (II) loading with 3.5 wt% to FAU-Y zeolite by incipient wetness impregnation method was shown higher nitric oxide conversion than aqueous solution ion exchange method.
硝酸还原Ni-FAU(Y)沸石的不同制备方法
在填充床反应器中,以氢气为反应物,采用水溶液离子交换法和初湿浸渍法制备了负载Ni阳离子的FAU(Y)沸石。在FAU(Y)沸石中装载了0.5 wt%和3.5 wt%的Ni (II)金属。采用x射线衍射、x射线荧光和扫描电镜对样品进行了表征。制备的Ni/FAU具有孔径较大的八面体晶体,孔径约为0.22±0.085 μm。Ni的加入对FAU(Y)分子筛的结构没有影响。初湿浸渍法将3.5 wt%的Ni (II)负载到fu - y分子筛上,其一氧化氮转化率高于水溶液离子交换法。
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