Dyeing performance of cotton fabrics with natural curcuminoid in supercritical carbon dioxide

W. Ju, Fu Wen-xiu
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Abstract

From 1980s, a new process for dyeing textiles using supercritical carbon dioxide instead of water was developed. When compared with conventional wet dyeing processes, supercritical carbon dioxide dyeing processes have many essential advantages, as carbon dioxide is a benign, nonflammable, non-toxic and inexpensive solvent, and its supercritical state is easy to get (the critical point of carbon dioxide is at 31.1 ̊C and 7.38MPa); in addition, after the dyeing process it can be readily recycled.3 Moreover, the energy and timeconsuming dry procedure is also no longer needed as the dyeing process is water free.4 Therefore, as an innovational and clean dyeing technology, supercritical carbon dioxide dyeing processes are more environmentally friendly and economically attractive for the textile industry.5 To date, the coloration of synthetic fibers, such as polyethylene terephthalate (PET),6 polylactides,7 polyamide 6 and 66,8 with disperse dyes in supercritical carbon dioxide has achieved commercial requirements. But it is still difficult for the dyeing of cotton fabrics in supercritical carbon dioxide. The main reason lies in the facts that disperse dyes have low affinity to cotton fibers.
天然姜黄素在超临界二氧化碳中的染色性能
从20世纪80年代开始,开发了一种用超临界二氧化碳代替水对纺织品染色的新工艺。与传统的湿法染色工艺相比,超临界二氧化碳染色工艺具有许多本质的优点,因为二氧化碳是一种良性、不易燃、无毒、廉价的溶剂,而且它的超临界状态很容易获得(二氧化碳的临界点为31.1℃,7.38MPa);此外,经过染色处理后,它可以很容易地回收利用此外,由于染色过程无水,也不再需要能量和耗时的干法因此,作为一种创新的清洁染色技术,超临界二氧化碳染色工艺对纺织工业更具环保和经济吸引力迄今为止,用分散染料在超临界二氧化碳中对聚对苯二甲酸乙二醇酯(PET)、聚乳酸酯、聚酰胺6和66,8等合成纤维进行染色已达到商业要求。但在超临界二氧化碳环境下对棉织物进行染色仍存在一定的困难。主要原因是分散染料对棉纤维的亲和力较低。
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