CHAPTER 20. Cavity Effects in Metal–Organic Frameworks

Víctor L. Rechac, Encarnación Peris Sanchis, F. X. L. I. Xamena
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引用次数: 1

Abstract

Metal–organic frameworks (MOFs) have attracted enormous interest in recent years owing to their potential use as heterogeneous catalysts. MOF catalysts can be designed with active sites at the metallic units or at the organic ligands or trapped inside their regular pore system. This chapter illustrates how cavity effects (i.e. the chemical environment in which the active sites are located) can have a large influence on their final catalytic properties through specific host–guest interactions, thereby introducing additional tools to modulate chemical specificity.
第20章。金属-有机骨架中的空腔效应
近年来,金属有机骨架(MOFs)因其作为多相催化剂的潜在用途而引起了人们的极大兴趣。MOF催化剂的活性位点可以设计在金属单元或有机配体上,或被困在其规则的孔隙系统中。本章阐述了空腔效应(即活性位点所在的化学环境)如何通过特定的主客体相互作用对其最终催化性能产生重大影响,从而引入了调节化学特异性的额外工具。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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