PPPS-2013: This is a sample abstract submission dielectric barrier discharges: Pulsed breakdown, electrical characterization and Chemistry

R. Brandenburg, H. Hoft, T. Hoder, A. Pipa, R. Basner, M. Schmidt, M. Kettlitz
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Abstract

Summary form only given. The application of atmospheric pressure discharges in new fields like environmental protection, surface treatment or life-sciences requires a profound knowledge on the plasma parameters and properties. This includes (1) the characterization of the breakdown processes triggering plasma chemistry, (2) the proper determination of the electrical parameters and (3) the description of the dominant chemical pathways. The contribution aims to present new approaches regarding these three topics for pulsed driven Dielectric Barrier Discharges in particular. It will be shown by fast electrical, optical and spectroscopic methods that the ignition, breakdown statistics and spatio-temporally resolved development of pulsed DBD microdischarges is controlled by the properties of the power supply (duty cycle, frequency, amplitude varied) as well as the composition of the gas1. In particular the starting point of the microdischarge ignition can be changed which is a new effect in DBDs caused by electric field rearrangement in the gap due to positive ion development. Surface processes at the dielectric barriers influencing this behavior will be discussed, too. The determination of electrical parameters such as discharge current, gas gap voltage, instantaneous power and energy as well as the charge transferred through the gas gap based on a simple equivalent circuit will be presented. The proposed approach accurately accounts the displacement current and key capacitance values, which inexactly determination are a source of experimental errors in particular in case of pulsed driven DBDs. The presented approach is consistent with sinusoidal-voltage driven or miniature pulsed driven DBDs. We believe that these new insights on electrical characterization are an important input for those who are working with DBDs, since the electrical parameters are mandatory information. The characterization of the dominant chemical pathways of advanced plasma processes is usually focused on the volume processes only. This contribution will discuss several examples which shall emphasize, that secondary effects must be considered, too. These shall cover the topics of adsorption-enhanced VOC conversion by DBD plasma treatment, NOx conversion and indirect plasma treatment of liquids for antimicrobial and chemical decontamination.
PPPS-2013:这是提交的样品摘要:介质阻挡放电:脉冲击穿,电学表征和化学
只提供摘要形式。大气压放电在环境保护、表面处理或生命科学等新领域的应用需要对等离子体的参数和特性有深刻的了解。这包括(1)触发等离子体化学的击穿过程的表征,(2)电参数的适当确定和(3)主要化学途径的描述。贡献的目的是提出关于这三个主题的新方法,特别是脉冲驱动的介质阻挡放电。通过快速电学、光学和光谱学方法表明,脉冲DBD微放电的点火、击穿统计和时空分辨发展是由电源的特性(占空比、频率、振幅变化)以及气体的组成控制的。特别是微放电点火的起始点可以改变,这是由于正离子在间隙中形成电场重排而引起的dbd的新效应。我们还将讨论介电势垒处的表面过程对这一特性的影响。给出了基于简单等效电路的放电电流、气隙电压、瞬时功率和能量以及通过气隙转移的电荷等电学参数的确定方法。提出的方法准确地计算位移电流和关键电容值,这些不准确的确定是实验误差的来源,特别是在脉冲驱动dbd的情况下。所提出的方法与正弦电压驱动或微型脉冲驱动dbd一致。我们相信这些关于电特性的新见解对于那些使用dbd的人来说是一个重要的输入,因为电参数是强制性的信息。对先进等离子体过程的主要化学途径的描述通常只集中在体积过程上。这篇文章将讨论几个例子,强调也必须考虑到次要影响。这些将涵盖DBD等离子体处理的吸附增强VOC转化、NOx转化和用于抗菌和化学净化的液体的间接等离子体处理等主题。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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