Theoretical Study of Heterogeneous Electronic Transition Rate at the Metal/ Ionic Liquid Interface Using Quantum Theory

B. Alshafaay, Hadi J. M. Al-Agealy, M. A. Hassooni
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Abstract

The purpose of this research is study the heterogeneous electronic transition through metal/liquid interface using simple model. The kinetic of electron transfer phenomenon discussion using postulate of quantum transition theory. The energy levels for metal and liquid assume to be alignment depending on continuum model theory. The behavour of electron transfer at metal-liquid interface affected by barrier height. The transition of negative charge on the interface of metal /liquid which suffering much more impediment to transfer cross the potential barrier .The net of electron that transfer give the average rate of electronic transfer and it indicate the electrical properties of metal/liquid devices.
金属/离子液体界面非均相电子跃迁速率的量子理论研究
本研究的目的是利用简单模型研究金属/液界面的非均相电子跃迁。用量子跃迁理论的假设讨论电子转移现象的动力学。根据连续介质模型理论,假设金属和液体的能级是对齐的。势垒高度对金属-液界面电子传递行为的影响。负电荷在金属/液体界面上的跃迁,在跨越势垒时受到更大的阻碍。电子转移网给出了电子转移的平均速率,并表示了金属/液体器件的电学性质。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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