Breakdown and space charge of LDPE films prepared using metallocene catalyst

T. Mori, R. Ishii, C. Banmongkol, T. Mizutani, M. Ishioka
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引用次数: 5

Abstract

Polyethylene (PE) has been widely used as electrical insulation for power cables because of its excellent electrical and mechanical properties. Low density PE (LDPE) prepared using a high pressure process has been widely used as insulating polymer of power cables. In this paper, the authors have investigated the performance of new LDPE prepared using metallocene catalyst (m-LDPE) as electrical insulating material. m-LDPE has narrower composition and molecular-weight distributions than LDPE. High-field electrical properties of m-LDPE at 90/spl deg/C were compared with those of the other LDPEs. In addition, the prestress effect and the effect of space charge on breakdown strength were discussed.
茂金属催化剂制备LDPE薄膜的击穿与空间电荷
聚乙烯(PE)由于其优异的电气性能和机械性能,被广泛用作电力电缆的电绝缘材料。采用高压法制备的低密度聚乙烯(LDPE)作为电力电缆的绝缘聚合物得到了广泛的应用。本文研究了以茂金属催化剂(m-LDPE)为电绝缘材料制备的新型LDPE的性能。m-LDPE比LDPE具有更窄的组成和分子量分布。比较了m-LDPE在90/spl度/C下的高场电性能。此外,还讨论了预应力效应和空间电荷对击穿强度的影响。
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