Corrosion inhibition of aluminium in 0.3 M HCl using starch mucor in potassium iodide as inhibitor

U. Ezeamaku, I. Eze, N. Odimegwu, Angela Nwakaudu, A. Okafor, O. Onukwuli, I. A. Nnanwube
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Abstract

Purpose The purpose of this study is to investigate starch mucor (SM) in potassium iodide (KI) as corrosion inhibitor of aluminium in hydrochloric acid (HCl) medium. Design/methodology/approach The SM in KI was characterized by gravimetric, scanning electron microscopy, electrochemical impedance spectroscopy measurements, potentiodynamic polarization and gas chromatography-mass spectrometer techniques. The inhibition efficiency was optimized using response surface methodology. Findings The result revealed that the inhibitor inhibited corrosion at a low concentration with the rate of inhibition increasing as the concentration of the inhibitor increased. The inhibition efficiency increases as the temperature was increased with slight incorporation of the inhibitor (SM in KI). This indicates that the corrosion control is both inhibitor (SM in KI) and temperature dependent. Originality/value The research results can provide the basis for using SM in KI as corrosion inhibitor of aluminium in HCL medium. Mixed-type inhibitor nature of SM was proved by cathodic and anodic nature of the polarization curves.
以淀粉毛霉为缓蚀剂的铝在0.3 M HCl中的缓蚀作用
目的研究淀粉毛霉(SM)在碘化钾(KI)中对铝在盐酸(HCl)介质中的缓蚀作用。采用重量、扫描电镜、电化学阻抗谱、动电位极化、气相色谱-质谱联用技术对KI中的SM进行了表征。采用响应面法优化抑菌效果。结果表明,缓蚀剂在低浓度下具有明显的缓蚀作用,缓蚀速率随缓蚀剂浓度的增加而增加。随着温度的升高,缓蚀剂(KI中的SM)掺入量的增加,缓蚀效率也随之提高。这表明,腐蚀控制既取决于缓蚀剂(KI中的SM),也取决于温度。研究结果可为KI中SM作为HCL介质中铝的缓蚀剂提供依据。极化曲线的阴极和阳极性质证明了SM的混合型缓蚀剂性质。
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