UV irradiation testing of biodiesel from the Alhagi oil and diesel-biodiesel mixtures

Abstract

The chemical stability of fuels is one of the key factors in ensuring the proper operation of combustion engines. Progressive destruction of components of diesel-biodiesel fuels during storage and transportation can adversely affect their physical and chemical parameters. Besides, the destruction of petroleum products under sunlight and the formation of toxic compounds have ecological importance. The purpose of the presented work is to investigate the influence of UV irradiation (λ = 300–450 nm) on the chemical content of petroleum diesel and B5, B10, B20, B50, and B100 fuel blends for the 24 h. As biodiesel, the product of transesterification of non-edible Alhagi oil with methanol was used. Chemical changes after irradiation were controlled by the BRUKER FT NMR spectrometer. The relationship between changes in the chemical composition and important physicochemical parameters (density, viscosity, flash point, and cetane index), before and after photochemical destructions was discussed. Based on the obtained results, it was determined that the B20 fuel mixture has more chemical stability after UV irradiation than conventional diesel and other diesel-biodiesel mixtures.