Nano Metal-Organic Framework Particles (i.e. MIL-100(Fe), HKUST-1(Cu), Cu-TPA, and MOF-5(Zn)) using a solvothermal process

Q1 Earth and Planetary Sciences
A. Nandiyanto
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引用次数: 6

Abstract

Metal-organic framework (MOF) is attractive because of its representation as a class of crystalline porous materials with excellent properties, specifically its chemical functionality and high porosity, making it potentially tailored for various desired applications. Although the synthesis of MOFs have been well-documented, most reports are in the bulk and micrometer sizes. The synthesis of MOFs in the smaller size is still inevitable. This work reports the synthesis of nano MOF particles (i.e., MIL-100(Fe), HKUST-1(Cu), Cu-TPA, and MOF-5(Zn)). In the experiment, MOFs were created by interacting ligands and metal ions in the specific solvent in the solvothermal process. Different from other reports, this study used low concentrations of ligands and metal ions, in which this is effective to control ligand-metal ion interaction, reaction, nucleation, and growth of MOF. The successful synthesis was obtained and effective for various MOF particles by changing types of ligands and metal ions. The study also obtained that compatibility and dilution of the ligands and the metal ions in the specific solvent are important parameters. This information will bring new strategies and further developments for the synthesis of MOF materials for wider range of potential applications in separation, catalysis, dye adsorption, and drug carrier uses.
纳米金属有机骨架粒子(即MIL-100(Fe), HKUST-1(Cu), Cu- tpa和MOF-5(Zn))采用溶剂热法
金属有机框架(MOF)具有优异的性能,特别是其化学功能和高孔隙率,使其有可能适合各种所需的应用,这是一类有吸引力的晶体多孔材料。虽然mof的合成已经有很好的文献记载,但大多数报道都是体积和微米尺寸的。小尺寸mof的合成仍是不可避免的。本文报道了纳米MOF颗粒(即MIL-100(Fe), HKUST-1(Cu), Cu- tpa和MOF-5(Zn))的合成。在实验中,通过溶剂热过程,通过配体和金属离子在特定溶剂中相互作用来制备mof。与其他报道不同的是,本研究使用了低浓度的配体和金属离子,有效地控制了配体与金属离子的相互作用、反应、成核和MOF的生长。通过改变配体和金属离子的类型,成功地合成了多种MOF颗粒。研究还发现配体与金属离子在特定溶剂中的相容性和稀释度是重要的参数。这些信息将为MOF材料的合成带来新的策略和进一步的发展,在分离、催化、染料吸附和药物载体等方面具有更广泛的潜在应用。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
Indonesian Journal of Science and Technology
Indonesian Journal of Science and Technology Engineering-Engineering (all)
CiteScore
11.20
自引率
0.00%
发文量
10
审稿时长
16 weeks
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