Macrostress in electrodeposited coatings determined by x-ray diffraction technique

L. Révay
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Abstract

Various metallic coatings deposited on different substrates have been investigated by means of X-rays to determine the macrostresses. The dependence of lattice strain on sin2 ψ obeys the linear relationship expected from the linear theory of elasticity.

The present study was intended to explore the possible application of X-ray macrostress measurement to surface coatings.

Measurement on gold electrodeposits revealed tensile stresses. After dissolution of the substrate (with intermediate nickel, copper or silver layer) the stress in the gold deposit changed to compressive. The stress of electrodeposited nickel was compressive; dissolution of the aluminium substrate reduced the stress level. Electrodeposited zinc coatings showed compressive stresses. The macrostresses are expressed in terms of proportional stresses to distinguish them from the absolute stress values.

用x射线衍射技术测定电沉积涂层中的宏观应力
用x射线研究了沉积在不同基底上的各种金属涂层的宏观应力。晶格应变对sin2 ψ的依赖符合弹性线性理论所期望的线性关系。本研究旨在探讨x射线大应力测量在表面涂层中的应用。对金镀层的测量显示了拉应力。在基材(中间有镍、铜或银层)溶解后,金矿中的应力变为压应力。电沉积镍的应力为压应力;铝基体的溶解降低了应力水平。电沉积锌涂层表现出压应力。宏观应力用比例应力表示,以区别于绝对应力值。
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