Selective guest recognition by a metallo-organic phthalocyanine-based host

Abstract

In this manuscript, we have studied the selectivity in the complexation of fullerene species by a Fe[Formula: see text]Pc[Formula: see text] metallo-organic helicate (1) assembled using a bidentate phthalocyanine (Pc) as ligand. The large aromatic internal surface of this helicate shows a strong selectivity towards the encapsulation of C[Formula: see text] from a mixture of C[Formula: see text] and C[Formula: see text]. On the other hand, a bisimidazole-containing naphthalenediimide was used to perform guest exchange experiments over [fullerene [Formula: see text] 1] complexes, taking advantage of the strong coordination bond of the imidazole ring to the Zn centers in the Pc cavity.