P.M. Kerimov, O.M. Alesgerova, L.M. Saadova, G. G. Nasibova, E.M. Guliyeva
{"title":"The synthesis of bis-dibenzoat, bis-p-dichloro-dibenzoat ethers of ethylene-glycol in the presence of ionic-liquid catalyst","authors":"P.M. Kerimov, O.M. Alesgerova, L.M. Saadova, G. G. Nasibova, E.M. Guliyeva","doi":"10.37474/0365-8554/2022-9-55-59","DOIUrl":null,"url":null,"abstract":"Bis-dibenzoat and bis-p-dichloro-dibenzoat ethers of ethylene-glycol with 82–92 % of yield correspondingly were synthesized based on the benzoic, p-chlorobenzoic acids and ethylene-glycol in the ratio of 2:1,2, at 110 оС temperature and 6-7 hours of reaction duration in the presence of ionic liquid catalyst of n-methylpirralidon-hydrosulphate. The physical-chemical parameters of synthesized compound ethers have been specified and their structure identified spectrally. Synthesized compound ethers have been tested on the steadiness of diesel fuel against thermal oxidation.","PeriodicalId":8668,"journal":{"name":"Azerbaijan Oil Industry","volume":"13 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2022-09-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Azerbaijan Oil Industry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.37474/0365-8554/2022-9-55-59","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
Bis-dibenzoat and bis-p-dichloro-dibenzoat ethers of ethylene-glycol with 82–92 % of yield correspondingly were synthesized based on the benzoic, p-chlorobenzoic acids and ethylene-glycol in the ratio of 2:1,2, at 110 оС temperature and 6-7 hours of reaction duration in the presence of ionic liquid catalyst of n-methylpirralidon-hydrosulphate. The physical-chemical parameters of synthesized compound ethers have been specified and their structure identified spectrally. Synthesized compound ethers have been tested on the steadiness of diesel fuel against thermal oxidation.