Anti-Corrosion Properties of Ions Modified Zeolite

M. Danyliak, O. Khlopyk, I. Zin, S. Korniy, M. Holovchuk
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Abstract

Environmentally friendly corrosion inhibitors were obtained by liquid-phase ion exchange modification of zeolite with zinc, calcium and manganese cations. The surface morphology and chemical composition of modified zeolites were determined by scanning electron microscopy and energy dispersion spectroscopy analyzes. It was established that the structure of ion-exchange modified zeolites is homogeneous with a particle size of 2-4 $\mu \mathrm{m}$. It was shown that using of modified zeolites increases the corrosion resistance of the aluminum alloy in 0.1% NaCl solution. The Zn-zeolite had highest anti-corrosion effectiveness. Gradual release of the inhibitory components from zeolites provides long-term protection of metal constructions.
离子改性沸石的防腐性能
采用锌、钙、锰阳离子对沸石进行液相离子交换改性,制备了环保型缓蚀剂。通过扫描电镜和能谱分析对改性沸石的表面形貌和化学成分进行了测定。结果表明,离子交换改性沸石结构均匀,粒径为2 ~ 4 $\mu \mathrm{m}$。结果表明,改性沸石的加入提高了铝合金在0.1% NaCl溶液中的耐蚀性。锌分子筛的防腐效果最好。沸石中抑制成分的逐渐释放为金属结构提供了长期的保护。
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