Synthesis and Physicochemical Study of Xanthan Butyl Ether

IF 0.5 Q4 CHEMISTRY, MULTIDISCIPLINARY
A. Kazachenko, O. Fetisova, A. V. Antonov, G. Bondarenko, V. V. Sychev
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引用次数: 2

Abstract

Xanthan is an important polysaccharide widely used in many industrial fields. It is produced by the bacteria Xanthomonascampestris. Chemical modification of xanthan can open up new horizons for its use. In this work, xanthan butyl ester was obtained for the first time by the interaction of xanthan and bromobutane using sodium hydroxide as a catalyst. The composition and structure of the obtained new xanthan derivative was studied by elemental analysis, IR spectroscopy, X-ray phase analysis, scanning electron microscopy and thermal analysis. The introduction of a butyl group into the xanthan molecule was proved by elemental analysis and IR spectroscopy by the appearance of corresponding bands. It was shown by X-ray phase analysis that xanthan butyl ether has a more X-ray amorphous structure in comparison with the original xanthan. It was shown by scanning electron microscopy that xanthan butyl ether powder consists of particles of a larger size and a layered structure in comparison with the original xanthan. It has been shown by thermal analysis that xanthan butyl ether is less thermostable than the starting xanthan
黄原胶丁基醚的合成及理化研究
黄原胶是一种重要的多糖,广泛应用于许多工业领域。它是由黄单胞菌产生的。对黄原胶进行化学改性,为其开发利用开辟了新的前景。本文首次以氢氧化钠为催化剂,由黄原胶与溴丁烷相互作用制得黄原胶丁基酯。采用元素分析、红外光谱、x射线物相分析、扫描电镜和热分析等方法对合成的新黄原胶衍生物的组成和结构进行了研究。通过元素分析和红外光谱分析,发现黄原胶分子中引入了丁基。x射线相分析表明,黄原胶丁基醚与原黄原胶相比,具有更多的x射线无定形结构。扫描电镜结果表明,与原黄原胶相比,原黄原胶丁基醚粉末颗粒尺寸更大,具有层状结构。热分析表明,黄原胶丁基醚的热稳定性低于起始黄原胶
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来源期刊
CiteScore
1.10
自引率
0.00%
发文量
13
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