Modified Natural Rubber Sir-20 Using Chain Scission Reaction Method And Grafting With Anhydrous Maleic

A. Sinaga, Eddyanto Eddyanto, Andreas Nababan
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Abstract

In this research, natural rubber SIR-20 was modified by the chain severing reaction method with the addition of decimal peroxide and flowing oxygen gas as much as 2 l/mint for 6 hours at a temperature of 135oC while stirring. Fourier Transformed-Infra Red (FTIR) spectra obtained, it can be concluded that there has been a chain breaking reaction seen from the functional group analysis which produces a series of distinctive peaks in the hydroxyl group (OH) and 2 carbonyl peaks (C=O) which are obtained at natural rubber SIR-20 + 3 phr DCP of 3435 and 1715, respectively; 1737 and has a strong intensity which indicates a chain breaking reaction has occurred in natural rubber SIR-20. From the results of the FTIR analysis, it was found that the C=O group was getting sharper which was the typical absorption peak originating from maleic anhydride grafted on the natural rubber chain.
用链裂反应法和无水马来酸接枝改性天然橡胶Sir-20
本研究以天然橡胶SIR-20为原料,在135℃的温度下,加入2 l/mint的过氧化物和流动的氧气,搅拌6小时,采用断链反应法进行改性。傅里叶变换-红外光谱(FTIR)分析表明,天然橡胶在SIR-20 + 3phr DCP分别为3435和1715时发生了断链反应,在羟基(OH)上产生了一系列独特的峰和2个羰基(C=O)峰;1737具有很强的强度,表明天然橡胶SIR-20中发生了断链反应。FTIR分析发现,C=O基团越来越尖锐,这是天然橡胶链上接枝马来酸酐的典型吸收峰。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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