Characteristics and Crystal Structure of Calcareous Deposit Films Formed by Electrodeposition Process in Artificial and Natural Seawater

Abstract

In this study, we tried to form the calcareous deposit films by the electrodeposition process. The uniform and compact calcareous deposit films were formed by electrodeposition process and their crystal structure and characteristics were analyzed and evaluated using various surface analytical techniques. The mechanism of formation for the calcareous deposit films could be confirmed and the role of magnesium was verified by experiments in artificial and natural seawater solutions. The highest amount of the calcareous deposit film was obtained at 5 A/m2 while current densities between 1–3 A/m2 facilitated the formation of the most uniform and dense layers. In addition, the adhesion characteristics were found to be the best at 3 A/m2. The excellent characteristics of the calcareous deposit films were obtained when the dense film of brucite-Mg(OH)2 and metastable aragonite-CaCO3 was formed in the appropriate ratio.