Adsorption properties of thiol-functionalized mesoporous silica

S. Kozlova, V. Parfenov, S. Kirik
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引用次数: 2

Abstract

Normal 0 false false false RU X-NONE X-NONE The synthesis and physico-chemical characteristics of thiol-functionalized mesoporous silicates MCM-41 and SBA-15 are described. The sorption properties of the materials with respect to noble metal ions, in particular palladium(II) from hydrochloric acid solutions have been studied. The materials obtained have been characterized using a complex of physical and chemical methods before and after functionalization. The evaluation of the sorption capacity of the obtained sorbents with respect to Pd(II) ions has been performed. Experimental results show high sorption activity of thiol-functionalized mesoporous silica /* Style Definitions */ table.MsoNormalTable {mso-style-name:"Обычная таблица"; mso-tstyle-rowband-size:0; mso-tstyle-colband-size:0; mso-style-noshow:yes; mso-style-priority:99; mso-style-qformat:yes; mso-style-parent:""; mso-padding-alt:0cm 5.4pt 0cm 5.4pt; mso-para-margin:0cm; mso-para-margin-bottom:.0001pt; mso-pagination:widow-orphan; font-size:11.0pt; font-family:"Calibri","sans-serif"; mso-ascii-font-family:Calibri; mso-ascii-theme-font:minor-latin; mso-fareast-font-family:"Times New Roman"; mso-fareast-theme-font:minor-fareast; mso-hansi-font-family:Calibri; mso-hansi-theme-font:minor-latin; mso-bidi-font-family:"Times New Roman"; mso-bidi-theme-font:minor-bidi;}
巯基功能化介孔二氧化硅的吸附性能
描述了巯基功能化介孔硅酸盐MCM-41和SBA-15的合成及其物理化学特性。研究了该材料对贵金属离子的吸附性能,特别是对盐酸溶液中钯离子的吸附性能。所得到的材料在功能化前后用物理和化学的复合方法进行了表征。对所获得的吸附剂对Pd(II)离子的吸附能力进行了评价。实验结果表明,巯基功能化介孔二氧化硅具有较高的吸附活性/*类型定义*/表。MsoNormalTable {mso-style-name:“Обычнаятаблица”;mso-tstyle-rowband-size: 0;mso-tstyle-colband-size: 0;mso-style-noshow:是的;mso-style-priority: 99;mso-style-qformat:是的;mso-style-parent:“”;Mso-padding-alt:0cm 5.4pt;mso-para-margin: 0厘米;mso-para-margin-bottom: .0001pt;mso-pagination: widow-orphan;字体大小:11.0分;字体类型:“Calibri”、“无衬线”;mso-ascii-font-family: Calibri;mso-ascii-theme-font: minor-latin;mso-fareast-font-family:宋体;mso-fareast-theme-font: minor-fareast;mso-hansi-font-family: Calibri;mso-hansi-theme-font: minor-latin;mso-bidi-font-family:宋体;mso-bidi-theme-font: minor-bidi;}
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