Preparation of SiC/LDPE nanocomposites surface modified by KH-560 and its space charge property

Quan Zhou, Chao Sun, Ke Wu, Di Zou, Jingshu Liao
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引用次数: 1

Abstract

The space charge distribution of the polymer is an important factor affecting the insulating properties. This paper studies the characteristics of space charge distribution of SiC/LDPE nanocomposites surface modified by the coupling agent KH-560. The experimental results show that the interface between the nano-SiC particles and polyethylene itself is the main source of the trap, and add different nano-particles have different implications on space charge distribution of nanocomposites, and there is a certain inhibition of the charge injection of the same polarity. It can be analyzed that the coupling agent has important implications on the nature and level of the traps, because of the coupling agent KH-560 molecule containing asymmetric side chain and terminal group structure which prone to deep traps with negative polarity tendency. The modified SiC/LDPE nanocomposites have good suppression effect of space charge injection and its migration, which helps enhancing the electrical properties of LDPE.
KH-560改性SiC/LDPE纳米复合材料的制备及其空间电荷性能
聚合物的空间电荷分布是影响其绝缘性能的重要因素。研究了偶联剂KH-560改性SiC/LDPE纳米复合材料表面的空间电荷分布特性。实验结果表明,纳米sic颗粒与聚乙烯本身之间的界面是陷阱的主要来源,添加不同的纳米颗粒对纳米复合材料的空间电荷分布有不同的影响,并且对相同极性的电荷注入有一定的抑制作用。由于偶联剂KH-560分子的侧链和端基结构不对称,容易形成具有负极性倾向的深阱,因此偶联剂对陷阱的性质和水平有重要影响。改性SiC/LDPE纳米复合材料具有良好的抑制空间电荷注入及其迁移的效果,有助于提高LDPE的电学性能。
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