Effect of poly(ethylene glycol) additives on the photocatalytic activity of TiO2 films prepared by sol–gel processing and low temperature treatments

Leo Chau-Kuang Liau , Hsuan Chang , Thomas Chun-Kuang Yang , Chien-Lung Huang
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引用次数: 25

Abstract

Photocatalytic activity of titania with poly(ethylene glycol) (PEG) in the sample films made under different operating conditions was investigated by kinetic analysis of photodegradation tests. The sample films, composed of PEG and nano-TiO2 particles, were prepared by sol–gel processing and then treated thermally under an atmosphere of wet and dry air at different temperatures. After the thermal treatment, photocatalytic activities of the films were evaluated by a UV-exposure test. Results showed that the photoactivity was enhanced by processing in an atmosphere of wet air at 100 °C. Moreover, the presence of poly(ethylene glycol), and the change in surface morphology in the sample films were verified to be the most influential and significant factors to affect the photoactivitic activity.

聚乙二醇添加剂对溶胶-凝胶法制备TiO2薄膜光催化活性的影响
通过光降解实验的动力学分析,考察了不同操作条件下制备的聚乙二醇(PEG)膜对二氧化钛的光催化活性。采用溶胶-凝胶法制备由PEG和纳米tio2颗粒组成的样品膜,然后在不同温度的干湿空气气氛下进行热处理。热处理后,通过紫外曝光试验评价了膜的光催化活性。结果表明,在100°C的湿空气中处理后,其光活性得到增强。此外,聚乙二醇的存在和样品膜表面形貌的变化是影响光活性的最重要因素。
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