Biodiesel Production from Cassia tora Seed Oil Through Acid-Base Catalysed Method

Hayatuddeen Abubakar, A. Hammari, A. Abubakar, A. Maiwada
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Abstract

Biodiesel produced from different triglyceride sources is an alternative fuel to petro-diesel. An investigation was carried out with Cassia tora seed oil. The oil was esterified to reduce the FFA content in the oil and trans-esterification of the oil was carried out which involves making use of methanol and sodium hydroxide pellets in a base-catalyzed trans-esterification reaction. 187g Cassia tora oil was trans-esterified with 20 g of methanol and 0.7 g of NaOH pellets at 55°C operating temperature. The outcome was a percentage conversion of 90.53 per cent for Cassia tora feedstock and a by-product of 15.20 g of glycerol (i.e. soap). The physical features of the oil, such as smell and colour, were retained in the biodiesel produced. The density of biodiesel made from Cassia tora oil was determined to be 848.0 kg/m3. The flashpoint was determined to be 135 oC and the acid value and water content were 0.16 (MgKOH/g) and 0.04 (per cent mass), respectively. The kinematic and dynamic viscosities of the generated biodiesel were 4.2mm2/s and 6.49 x 10-3kgm-1s-1, respectively. The pour point was also discovered to be -6 oC. The biodiesel was evaluated using American testing and material standards (ASTM Values). Based on the comparison of measured characteristics with ASTM values, Cassia tora seed oil could be a promising option for biodiesel production
酸碱催化决明子油制备生物柴油
由不同甘油三酯来源生产的生物柴油是石油柴油的替代燃料。对决明子油进行了研究。将油进行酯化以降低油中游离脂肪酸的含量,并利用甲醇和氢氧化钠球团进行碱催化的反式酯化反应。187g决明子油与20g甲醇和0.7 g NaOH球团在55°C操作温度下进行反式酯化。结果是决明子原料的转化率为90.53%,副产品为15.20 g甘油(即肥皂)。油的物理特性,如气味和颜色,被保留在生产的生物柴油中。测定决明子油制备生物柴油的密度为848.0 kg/m3。测定其闪点为135℃,酸值为0.16 (MgKOH/g),含水量为0.04(%质量)。所得生物柴油的运动粘度为4.2mm2/s,动态粘度为6.49 × 10-3kgm-1s-1。浇注点也被发现为-6℃。采用美国测试和材料标准(ASTM值)对生物柴油进行了评估。根据测量特性与ASTM值的比较,决明子籽油可能是生产生物柴油的有前途的选择
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