I. Kelnar, J. Kratochvíl, L. Kaprálková, Z. Špitalský, Massimo Ujčič, A. Zhigunov, M. Nevoralová
{"title":"Effect of Graphene Oxide on Structure and Properties of Impact-Modified Polyamide 6","authors":"I. Kelnar, J. Kratochvíl, L. Kaprálková, Z. Špitalský, Massimo Ujčič, A. Zhigunov, M. Nevoralová","doi":"10.1080/03602559.2017.1354223","DOIUrl":null,"url":null,"abstract":"ABSTRACT Modification of polymer blends with nanofillers is an efficient way to improve material parameters. This work deals with application of neat and stearylamine-modified graphene oxide in the polyamide 6/elastomer system using different mixing protocols. Combination of ethene–propene elastomer and graphene oxide leads to a polyamide material with increased strength, stiffness, and toughness. The reason is synergistic effect of the core–shell structure (nanofiller localized at interface) on mechanical properties. The structure-directing effect of graphene oxide is comparable with that of nanoclay. The mechanism of affecting dynamic phase behavior is different as a consequence of graphene oxide nature and interactions with polymer components. GRAPHICAL ABSTRACT","PeriodicalId":20629,"journal":{"name":"Polymer-Plastics Technology and Engineering","volume":"15 1","pages":"827 - 835"},"PeriodicalIF":0.0000,"publicationDate":"2018-06-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"14","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Polymer-Plastics Technology and Engineering","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1080/03602559.2017.1354223","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"Materials Science","Score":null,"Total":0}
引用次数: 14
Abstract
ABSTRACT Modification of polymer blends with nanofillers is an efficient way to improve material parameters. This work deals with application of neat and stearylamine-modified graphene oxide in the polyamide 6/elastomer system using different mixing protocols. Combination of ethene–propene elastomer and graphene oxide leads to a polyamide material with increased strength, stiffness, and toughness. The reason is synergistic effect of the core–shell structure (nanofiller localized at interface) on mechanical properties. The structure-directing effect of graphene oxide is comparable with that of nanoclay. The mechanism of affecting dynamic phase behavior is different as a consequence of graphene oxide nature and interactions with polymer components. GRAPHICAL ABSTRACT