NMR studies of the electronic structure of low-spin iron(III) phosphonite complexes: unusual (dxz, dyz)4(dxy)1 configuration

M. Guillemot, G. Simonneaux
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引用次数: 6

Abstract

Complexation of dimethylphenylphosphonite to (5,10,15,20-tetraphenylporphyrinato)iron(III) yields a low-spin derivative [Fe(tpp){P(OMe)2Ph}2]ClO4, showing NMR and EPR properties consistent with an iron(III) ion in the unusual ground-state configuration(dxy,dyz)4(dxy)1.
低自旋铁(III)膦酸盐配合物电子结构的核磁共振研究:异常(dxz, dyz)4(dxy)1构型
二甲基苯基膦酸盐与(5,10,15,20-四苯基卟啉)铁(III)络合得到低自旋衍生物[Fe(tpp){P(OMe)2Ph}2]ClO4,显示出与铁(III)离子在不寻常的基态构型(dxy,dyz)4(dxy)1下的NMR和EPR性质一致。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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