Influence of magnesia in the infiltration of magnesia-spinel refractory bricks by different clinkers

Abstract

In cement production, which involves the production of cement clinker in rotary kilns, the main refractories used are magnesia-spinel bricks. These bricks may suffer infiltration by the clinker liquid phase, resulting in the corrosion of the spinel and the formation of low refractoriness mineralogical phases, such as the Q phase (C 20 A 13 M 3 S 3 ), which compromises refractory performance. Thus, the aim of this work is to correlate the infiltration resistance of magnesia-spinel bricks made from different grades of magnesia by clinker collected in three different cement plants (A, B and C). The purity of magnesia, besides its physical properties, strongly influences the proper ties and the infiltration resistance of magnesia-spinel bricks; as such the use of high grade magnesia is essential for producing high performance refractories.