Трёхмерная микроспектроскопия оптических центров в цветных природных алмазах

Е.Н. Римская, Е. В. Кузьмин, П. А. Данилов, Г.Ю. Криулина, Д.А. Помазкин, С. И. Кудряшов
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Abstract

A study of three-dimensional photoluminescence of natural diamonds of two types, differing in morphology and absorption in the infrared range, was carried out. It is shown that, depending on the type and concentration of nitrogen defects in natural diamond, the position of the absorption band maximum can shift, which determines the pink or brown color of diamonds. The results of the study were carried out photoluminescence spectra at two pump wavelengths (488 and 532 nm), which make it possible to determine the optical centers that contribute to the color of diamonds. It is shown that complex nitrogen defects appear in natural colored diamonds as a result of plastic deformation, which determine the properties of the diamond.
彩色天然钻石光学中心三维显微光谱学
对两种形态和红外吸收不同的天然金刚石进行了三维光致发光研究。结果表明,根据天然金刚石中氮缺陷的类型和浓度的不同,最大吸收带的位置会发生位移,从而决定了金刚石的粉红色或棕色。研究结果是在两个泵浦波长(488 nm和532 nm)的光致发光光谱下进行的,这使得确定影响钻石颜色的光学中心成为可能。结果表明,天然彩色金刚石在塑性变形过程中会出现复杂的氮缺陷,而氮缺陷决定了金刚石的性能。
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