Study to Evaluate Photocatalytic Decomposition of Several Organic Compounds and Self-Cleaning Ability of Fabrics Containing ZnO

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Abstract

ZnO's ability to decompose organic substances is receiving much attention in multiple applications. ZnO has a broad spectrum of light absorption natural or synthetic, for a wide range of wavelengths, and is an important material with excellent properties, environmentally friendly, nontoxic, inexpensive, and high redox potential features with simple manufacturing methods. In this study, zinc oxide nanoparticles were synthesized by precipitation method with the participation of precursors (CH3COO)2Zn.2H2O and KOH. The surface morphology, chemical properties, and chemical composition of the ZnO catalyst were characterized by X-ray diffraction (XRD), Scanning Electron Microscopy, and Energy-Dispersive X-ray Spectroscopy (SEM-EDS). The photocatalytic activity of ZnO was evaluated with the color change of methylene blue (MB), methylene orange (MO), and diluted coffee solutions. The results show that ZnO has a high photocatalytic activity with a decomposition ability of over 90% for MO and MB pigments, and over 40% for a coffee solution when irradiated under ultraviolet light. This study's cotton fabric impregnated with ZnO showed good self-cleaning effects against organic pigments, which are MB, MO, and coffee. The results were demonstrated by the color changes over a 19-h period of time.
含ZnO织物的光催化分解及自洁性能研究
氧化锌分解有机物的能力在多种应用中受到广泛关注。ZnO具有天然或合成的广谱光吸收,波长范围广,制造方法简单,性能优异,环保、无毒、价格低廉、氧化还原电位高等特点,是一种重要的材料。在前驱体(CH3COO)2Zn的参与下,采用沉淀法合成了氧化锌纳米颗粒。2H2O和KOH。采用x射线衍射(XRD)、扫描电子显微镜(SEM-EDS)和能量色散x射线能谱(SEM-EDS)表征了ZnO催化剂的表面形貌、化学性质和化学成分。通过亚甲基蓝(MB)、亚甲基橙(MO)和稀释咖啡溶液的颜色变化来评价ZnO的光催化活性。结果表明,ZnO具有较高的光催化活性,在紫外光照射下,氧化锌对MO和MB色素的分解率超过90%,对咖啡溶液的分解率超过40%。本研究用氧化锌浸渍棉织物,对MB、MO、咖啡等有机色素具有良好的自清洁效果。结果通过19小时的颜色变化来证明。
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